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Mendelevium,  101Md
General properties
Name, symbol mendelevium, Md
Pronunciation or
Mendelevium in the periodic table


Atomic number 101
Standard atomic weight (258)
Element category actinide
Group, block group n/a, f-block
Period period 7
Electron configuration [Rn] 5f13 7s2
per shell 2, 8, 18, 32, 31, 8, 2
Physical properties
Phase solid (predicted)
Melting point 1100 K ​(827 °C, ​1521 °F) (predicted)
Atomic properties
Oxidation states 2, 3
Electronegativity Pauling scale: 1.3
Ionization energies 1st: 635 kJ·mol−1
CAS number 7440-11-1
Naming after Dmitri Mendeleev
Discovery Lawrence Berkeley National Laboratory (1955)
Most stable isotopes
iso NA half-life DM DE (MeV) DP
257Md syn 5.52 h ε 0.406 257Fm
α 7.558 253Es
258Md syn 51.5 d ε 1.230 258Fm
260Md syn 31.8 d SF
α 7.000 256Es
ε 260Fm
β 1.000 260No

Mendelevium is a synthetic element with chemical symbol Md (formerly Mv) and atomic number 101. A metallic radioactive transuranic element in the actinide series, it is the first element that currently cannot be produced in macroscopic quantities through neutron bombardment of lighter elements. It is the antepenultimate actinide and the ninth transuranic element. It can only be produced in particle accelerators by bombarding lighter elements with charged particles. A total of sixteen mendelevium isotopes are known, the most stable being 258Md with a half-life of 51 days; nevertheless, the shorter-lived 256Md (half-life 1.27 hours) is most commonly used in chemistry because it can be produced on a larger scale.

Mendelevium was discovered by bombarding einsteinium with alpha particles in 1955, the same method still used to produce it today. It was named after Dmitri Mendeleev, father of the periodic table of the chemical elements. Using available microgram quantities of the isotope einsteinium-253, over a million mendelevium atoms may be produced each hour. The chemistry of mendelevium is typical for the late actinides, with a preponderance of the +3 oxidation state but also an accessible +2 oxidation state. Owing to the small amounts of produced mendelevium and all of its isotopes having relatively short half-lives, there are currently no uses for it outside of basic scientific research.


Black-and-white picture of heavy machinery with two operators sitting aside
The 60-inch cyclotron at the Lawrence Radiation Laboratory, University of California, Berkeley, in August 1939

Mendelevium was the ninth Stanley G. Thompson in early 1955 at the University of California, Berkeley. The team produced 256Md (half-life of 87 minutes) when they bombarded an 253Es target consisting of only a billion (109) einsteinium atoms with alpha particles (helium nuclei) in the Berkeley Radiation Laboratory's 60-inch cyclotron, thus increasing the target's atomic number by two. 256Md thus became the first isotope of any element to be synthesized one atom at a time. In total, seventeen mendelevium atoms were produced.[1] This discovery was part of a program, begun in 1952, that irradiated plutonium with neutrons to transmute it into heavier actinides.[2] This method was necessary as the previous method used to synthesize transuranic elements, neutron capture, could not work because of a lack of beta decaying isotopes of fermium that would produce isotopes of the next element, mendelevium, and also due to the very short half-life to spontaneous fission of fermium-258 that thus constituted a hard limit to the success of the neutron capture process.[3]

To predict if the production of mendelevium would be possible, the team made use of a rough calculation. The number of atoms that would be produced would be approximately equal to the product of the number of atoms of target material, the target's cross section, the ion beam intensity, and the time of bombardment; this last factor was related to the half-life of the product when bombarding for a time on the order of its half-life. This gave one atom per experiment. Thus under optimum conditions, the preparation of only one atom of element 101 per experiment could be expected. This calculation demonstrated that it was feasible to go ahead with the experiment.[1] The target material, einsteinium-253, could be produced readily from irradiating [2]

The data sheet, showing stylus tracing and notes, that proved the discovery of mendelevium.

While Seaborg applied for funding, Harvey worked on the einsteinium target, while Thomson and Choppin focused on methods for chemical isolation. Choppin suggested using α-hydroxyisobutyric acid to separate the mendelevium atoms from those of the lighter actinides.[2] The actual synthesis was done by a recoil technique, introduced by Albert Ghiorso. In this technique, the einsteinium was placed on the opposite side of the target from the beam, so that the recoiling mendelevium atoms would get enough momentum to leave the target and be caught on a catcher foil made of gold. This recoil target was made by an electroplating technique, developed by Alfred Chetham-Strode. This technique gave a very high yield, which was absolutely necessary when working with such a rare and valuable product as the einsteinium target material.[1] The recoil target consisted of 109 atoms of 253Es which were deposited electrolytically on a thin gold foil. It was bombarded by 41 MeV alpha particles in the Berkeley cyclotron with a very high beam density of 6×1013 particles per second over an area of 0.05 cm2. The target was cooled by water or liquid helium, and the foil could be replaced.[1][4]

Initial experiments were carried out in September 1954. No alpha decay was seen from mendelevium atoms; thus, Ghiorso suggested that the mendelevium had all decayed by electron capture to fermium and that the experiment should be repeated to search instead for spontaneous fission events.[2] The repetition of the experiment happened in February 1955.[2]

The element was named after Dmitri Mendeleev.

On the day of discovery, 19 February, alpha irradiation of the einsteinium target occurred in three three-hour sessions. The cyclotron was in the [2] Additional analysis and further experimentation showed the produced mendelevium isotope to have mass 256 and to decay by electron capture to fermium-256 with a half-life of 1.5 h.[3]

Being the first of the second hundred of the chemical elements, it was decided that the element would be named "mendelevium" after the Russian chemist United States to propose that the element be named for a Russian, but it was granted.[2] The name "mendelevium" was accepted by the International Union of Pure and Applied Chemistry (IUPAC) in 1955 with symbol "Mv",[7] which was changed to "Md" in the next IUPAC General Assembly (Paris, 1957).[8]



Energy required to promote an f electron to the d subshell for the f-block lanthanides and actinides. Above around 210 kJ/mol, this energy is too high to be provided for by the greater crystal energy of the trivalent state and thus einsteinium, fermium, mendelevium form divalent metals like the lanthanides europium and ytterbium. (Nobelium is also expected to form a divalent metal, but this has not yet been confirmed.)[9]

In the periodic table, mendelevium is located to the right of the actinide fermium, to the left of the actinide nobelium, and below the lanthanide thulium. Mendelevium metal has not yet been prepared in bulk quantities, and bulk preparation is currently impossible.[10] Nevertheless, a number of predictions and some preliminary experimental results have been done regarding its properties.[10]

The lanthanides and actinides, in the metallic state, can exist as either divalent (such as europium and ytterbium) or trivalent (most other lanthanides) metals. The former have fnd1s2 configurations, whereas the latter have fn+1s2 configurations. In 1975, Johansson and Rosengren examined the measured and predicted values for the cohesive energies (enthalpies of crystallization) of the metallic lanthanides and actinides, both as divalent and trivalent metals.[11][12] The conclusion was that the increased binding energy of the [Rn]5f126d17s2 configuration over the [Rn]5f137s2 configuration for mendelevium was not enough to compensate for the energy needed to promote one 5f electron to 6d, as is true also for the very late actinides: thus einsteinium, fermium, mendelevium, and nobelium were expected to be divalent metals.[11] The increasing predominance of the divalent state well before the actinide series concludes is attributed to the relativistic stabilization of the 5f electrons, which increases with increasing atomic number.[13] Thermochromatographic studies with trace quantities of mendelevium by Zvara and Hübener from 1976 to 1982 confirmed this prediction.[10] In 1990, Haire and Gibson estimated mendelevium metal to have an enthalpy of sublimation between 134 and 142 kJ·mol−1.[10] Divalent mendelevium metal should have a metallic radius of around (194 ± 10) pm.[10] Mendelevium's melting point has been estimated at 827 °C, the same value as that predicted for the neighboring element nobelium.[14]


The chemistry of mendelevium is mostly known only in solution, in which it can take on the +3 or +2 oxidation states. The +1 state has also been reported, but has not yet been confirmed.[15]

Before mendelevium's discovery, eluted just after fermium in the trivalent actinide elution sequence from a cation-exchange column of resin, and later the 1967 observation that mendelevium could form insoluble hydroxides and fluorides that coprecipitated with trivalent lanthanide salts.[15] Cation-exchange and solvent extraction studies led to the conclusion that mendelevium was a trivalent actinide with an ionic radius somewhat smaller than that of the previous actinide, fermium.[15] Mendelevium can form coordination complexes with 1,2-cyclohexanedinitrilotetraacetic acid (DCTA).[15]

In reducing conditions, mendelevium(III) can be easily reduced to mendelevium(II), which is stable in aqueous solution.[15] The standard reduction potential of the E°(Md3+→Md2+) couple has been variously estimated as −0.10 V or −0.20 V.[15] In comparison, E°(Md3+→Md0) should be around −1.74 V, and E°(Md2+→Md0) should be around −2.5 V.[15] Mendelevium(II)'s elution behavior has been compared with that of strontium(II) and europium(II).[15]

In 1973, mendelevium(I) was reported to have been produced by Russian scientists, who obtained it by reducing higher oxidation states of mendelevium with samarium(II). It was found to be stable in neutral water–ethanol solution and be homologous to caesium(I). However, later experiments found no evidence for mendelevium(I) and found that mendelevium behaved like divalent elements when reduced, not like the monovalent alkali metals.[15] Nevertheless, the Russian team conducted further studies on the thermodynamics of cocrystallizing mendelevium with alkali metal chlorides, and concluded that mendelevium(I) had formed and could form mixed crystals with divalent elements, thus cocrystallizing with them. The status of the +1 oxidation state is still tentative.[15]

Although E°(Md4+→Md3+) was predicted in 1975 to be +5.4 V, suggesting that mendelevium(III) could be easily oxidized to mendelevium(IV), 1967 experiments with the strong oxidizing agent sodium bismuthate were unable to oxidize mendelevium(III) to mendelevium(IV).[15]


A mendelevium atom has 101 electrons, of which at least three (and perhaps four) can act as valence electrons. They are expected to be arranged in the configuration [Rn]5f137s2 (ground state term symbol 2F7/2), although experimental verification of this electron configuration had not yet been made as of 2006.[16] In forming compounds, three valence electrons may be lost, leaving behind a [Rn]5f12 core: this conforms to the trend set by the other actinides with their [Rn] 5fn electron configurations in the tripositive state. The first ionization potential of mendelevium was measured to be at most (6.58 ± 0.07) eV in 1974, based on the assumption that the 7s electrons would ionize before the 5f ones;[17] this value has since not yet been refined further due to mendelevium's scarcity and high radioactivity.[18] The ionic radius of hexacoordinate Md3+ had been preliminarily estimated in 1978 to be around 91.2 pm;[15] 1988 calculations based on the logarithmic trend between distribution coefficients and ionic radius produced a value of 89.6 pm, as well as an enthalpy of hydration of −(3654 ± 12) kJ·mol−1.[15] Md2+ should have an ionic radius of 115 pm and hydration enthalpy −1413 kJ·mol−1; Md+ should have ionic radius 117 pm.[15]


Sixteen isotopes of mendelevium are known, with mass numbers from 245 to 260; all are radioactive.[19] Additionally, five nuclear isomers are known: 245mMd, 247mMd, 249mMd, 254mMd, and 258mMd.[20][3] Of these, the longest-lived isotope is 258Md with a half-life of 51.5 days, and the longest-lived isomer is 258mMd with a half-life of 58.0 minutes.[20][3] Nevertheless, the slightly shorter-lived 256Md (half-life 1.27 hours) is more often used in chemical experimentation because it can be produced in larger quantities from alpha particle irradiation of einsteinium.[19] After 258Md, the next most stable mendelevium isotopes are 260Md with a half-life of 31.8 days, 257Md with a half-life of 5.52 hours, 259Md with a half-life of 1.60 hours, and 256Md with a half-life of 1.27 hours. All of the remaining mendelevium isotopes have half-lives that are less than an hour, and the majority of these have half-lives that are less than 5 minutes.[19][20][3]

The half-lives of mendelevium isotopes mostly increase smoothly from 245Md onwards, reaching a maximum at 258Md.[19][20][3] Experiments and predictions suggest that the half-lives will then decrease, apart from 260Md with a half-life of 31.8 days,[19][20][3] as spontaneous fission becomes the dominant decay mode[3] due to the mutual repulsion of the protons posing a limit to the island of relative stability of long-lived nuclei in the actinide series.[21]

Mendelevium-256, the chemically most important isotope of mendelevium, decays through electron capture 90.7% of the time and alpha decay 9.9% of the time.[19] It is most easily detected through the spontaneous fission of its electron-capture daughter fermium-256, but in the presence of other nuclides that undergo spontaneous fission, alpha decays at the characteristic energies for mendelevium-256 (7.205 and 7.139 MeV) can provide more useful identification.[22]

Production and isolation

The lightest mendelevium isotopes (245Md to 247Md) are mostly produced through bombardment of bismuth targets with heavy argon ions, while slightly heavier ones (248Md to 253Md) are produced by bombarding plutonium and americium targets with lighter ions of carbon and nitrogen. The most important and most stable isotopes are in the range from 254Md to 258Md and are produced through bombardment of einsteinium isotopes with alpha particles: einsteinium-253, -254, and -255 can all be used. 259Md is produced as a daughter of 259No, and 260Md can be produced in a transfer reaction between einsteinium-254 and oxygen-18.[19] Typically, the most commonly used isotope 256Md is produced by bombarding either einsteinium-253 or -254 with alpha particles: einsteinium-254 is preferred when available because it has a longer half-life and therefore can be used as a target for longer.[19] Using available microgram quantities of einsteinium, femtogram quantities of mendelevium-256 may be produced.[19]

The recoil momentum of the produced mendelevium-256 atoms is used to bring them physically far away from the einsteinium target from which they are produced, bringing them onto a thin foil of metal (usually beryllium, aluminium, platinum, or gold) just behind the target in a vacuum.[22] This eliminates the need for immediate chemical separation, which is both costly and prevents reusing of the expensive einsteinium target.[22] The mendelevium atoms are then trapped in a gas atmosphere (frequently helium), and a gas jet from a small opening in the reaction chamber carries the mendelevium along.[22] Using a long capillary tube, and including potassium chloride aerosols in the helium gas, the mendelevium atoms can be transported over tens of meters to be chemically analyzed and have their quantity determined.[5][22] The mendelevium can then be separated from the foil material and other fission products by applying acid to the foil and then coprecipitating the mendelevium with lanthanum fluoride, then using a cation-exchange resin column with a 10% ethanol solution saturated with hydrochloric acid, acting as an eluant. However, if the foil is made of gold and thin enough, it is enough to simply dissolve the gold in aqua regia before separating the trivalent actinides from the gold using anion-exchange chromatography, the eluant being 6 M hydrochloric acid.[22]

Mendelevium can finally be separated from the other trivalent actinides using selective elution from a cation-exchange resin column, the eluant being ammonia α-HIB.[22] Using the gas-jet method often renders the first two steps unnecessary.[22] The above procedure is the most commonly used one for the separation of transeinsteinium elements.[22]

Another possible way to separate the trivalent actinides is via solvent extraction chromatography using [5][22]

Another method to isolate mendelevium exploits the distinct elution properties of Md2+ from those of Es3+ and Fm3+. The initial steps are the same as above, and employs HDEHP for extraction chromatography, but coprecipitates the mendelevium with terbium fluoride instead of lanthanum fluoride. Then, 50 mg of chromium is added to the mendelevium to reduce it to the +2 state in 0.1 M hydrochloric acid with zinc or mercury.[22] The solvent extraction then proceeds, and while the trivalent and tetravalent lanthanides and actinides remain on the column, mendelevium(II) does not and stays in the hydrochloric acid. It is then reoxidized to the +3 state using hydrogen peroxide and then isolated by selective elution with 2 M hydrochloric acid (to remove impurities, including chromium) and finally 6 M hydrochloric acid (to remove the mendelevium).[22] It is also possible to use a column of cationite and zinc amalgam, using 1 M hydrochloric acid as an eluant, reducing Md(III) to Md(II) where it behaves like the alkaline earth metals.[22] Thermochromatographic chemical isolation could be achieved using the volatile mendelevium hexafluoroacetylacetonate: the analogous fermium compound is also known and is also volatile.[22]


  1. ^ a b c d Ghiorso, A.; Harvey, B.; Choppin, G.; Thompson, S.; Seaborg, G. (1955). "New Element Mendelevium, Atomic Number 101". Physical Review 98 (5): 1518.  
  2. ^ a b c d e f g h Choppin, Gregory R. (2003). "Mendelevium". Chemical and Engineering News 81 (36). 
  3. ^ a b c d e f g h Audi, G.; Bersillon, O.; Blachot, J.; Wapstra, A. H. (2003), evaluation of nuclear and decay properties"UBASE"The N, Nucl. Phys. A 729: 3–128,  
  4. ^ Hofmann, Sigurd (2002). On beyond uranium: journey to the end of the periodic table. CRC Press&year=2002. pp. 40–42.  
  5. ^ a b c Hall, Nina (2000). The new chemistry. Cambridge University Press. pp. 9–11.  
  6. ^ 101. Mendelevium - Elementymology & Elements Multidict. Peter van der Krogt.
  7. ^ Chemistry, International Union of Pure and Applied (1955). Comptes rendus de la confèrence IUPAC. 
  8. ^ Chemistry, International Union of Pure and Applied (1957). Comptes rendus de la confèrence IUPAC. 
  9. ^ Haire, Richard G. (2006). "Einsteinium". In Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean. The Chemistry of the Actinide and Transactinide Elements 3 (3rd ed.). Dordrecht, the Netherlands: Springer. pp. 1577–1620.  
  10. ^ a b c d e Silva, pp. 1634–5
  11. ^ a b Silva, pp. 1626–8
  12. ^ Johansson, Börje; Rosengren, Anders (1975). "Generalized phase diagram for the rare-earth elements: Calculations and correlations of bulk properties". Physical Review B 11 (8): 2836.  
  13. ^ Hulet, E. K. (1980). "Chapter 12. Chemistry of the Heaviest Actinides: Fermium, Mendelevium, Nobelium, and Lawrencium". In Edelstein, Norman M. Lanthanide and Actinide Chemistry and Spectroscopy.  
  14. ^ Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed. ed.). CRC Press. pp. 4.121–4.123.  
  15. ^ a b c d e f g h i j k l m n Silva, pp. 1635–6
  16. ^ Silva, pp. 1633–4
  17. ^ Martin, W. C.; Hagan, Lucy; Reader, Joseph; Sugan, Jack (1974). "Ground Levels and Ionization Potentials for Lanthanide and Actinide Atoms and Ions". J. Phys. Chem. Ref. Data 3 (3): 771–9. Retrieved 2013-10-19. 
  18. ^ David R. Lide (ed), CRC Handbook of Chemistry and Physics, 84th Edition. CRC Press. Boca Raton, Florida, 2003; Section 10, Atomic, Molecular, and Optical Physics; Ionization Potentials of Atoms and Atomic Ions
  19. ^ a b c d e f g h i Silva, pp. 1630–1
  20. ^ a b c d e Nucleonica (2007–2014). "Universal Nuclide Chart". Nucleonica. Retrieved 22 May 2011. 
  21. ^ Nurmia, Matti (2003). "Nobelium". Chemical and Engineering News 81 (36). 
  22. ^ a b c d e f g h i j k l m n Silva, pp. 1631–3


  • Silva, Robert J. (2006). Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean, eds. "The Chemistry of the Actinide and Transactinide Elements" (PDF) 3 (3rd ed.). Dordrecht: Springer. pp. 1621–1651.  

Further reading

  • Hoffman, D.C., Ghiorso, A., Seaborg, G. T. The transuranium people: the inside story, (2000), 201–229
  • Morss, L. R., Edelstein, N. M., Fuger, J., The chemistry of the actinide and transactinide element, 3, (2006), 1630–1636
  • Seaborg, G. T., Les elements tranuraniens artificiels, (1967), 39–45
  • Gol’danskii, V. I., Polikanov, S. M., The transuranium elements, (1973), 101–103
  • Seaborg, G.T., The transcalifornium elements. Journal of Chemical Education, (1959), 36, 38–44
  • Guide to the Elements – Revised Edition, Albert Stwertka, (Oxford University Press; 1998) ISBN 0-19-508083-1

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