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Ruthenium tetroxide

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Title: Ruthenium tetroxide  
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Subject: Oxide, Oxidation of primary alcohols to carboxylic acids, Strontium ruthenate, Fission products (by element), Ruthenium
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Ruthenium tetroxide

Ruthenium(VIII) oxide
Identifiers
CAS number  YesY
PubChem
Properties
Molecular formula RuO4
Molar mass 165.07 g/mol
Appearance colorless liquid
Odor pungent
Density 3.29 g/cm3
Melting point 25.4 °C (77.7 °F; 298.5 K)
Boiling point 40.0 °C (104.0 °F; 313.2 K)
Solubility in water 2% w/v at 20 °C
Solubility in other solvents Soluble in
Carbon tetrachloride
Chloroform
Structure
Molecular shape tetrahedral
Dipole moment zero
Hazards
MSDS external MSDS sheet
NFPA 704
2
Related compounds
Related compounds RuO2
RuCl3
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
 YesY   YesY/N?)

Ruthenium tetroxide (Ruthenium(VIII) oxide) is the oxide, it is quite volatile. The analogous OsO4 is more widely used and better known. One of the few solvents in which it forms stable solutions is CCl4.

Preparation

RuO4 is prepared by oxidation of ruthenium(III) chloride with NaIO4.

8 Ru3+(aq) + 5 IO4(aq) + 12 H2O(l) → 8 RuO4(s) + 5 I(aq) + 24 H+(aq)

In typical reactions featuring RuO4 as the oxidant, many forms of ruthenium usefully serve as precursors to RuO4, such as oxide hydrates or hydrated chloride.

Structure

The molecule adopts tetrahedral. The Ru-O distances range from 169 to 170 pm.[1]

Properties, uses, related reagents

RuO4 is diamagnetic.

It oxidizes virtually any hydrocarbon. For example, it will oxidize alkynes to 1,2-diketones and primary alcohols to carboxylic acids. When used in this fashion, the ruthenium(VIII) oxide is used in catalytic amounts and regenerated by the addition of sodium periodate to ruthenium(III) chloride and a solvent mixture of acetonitrile, water and carbon tetrachloride.

Because it is such an aggressive oxidant, reaction conditions are mild, generally room temperature. Although a strong oxidant, RuO4 oxidations do not perturb stereocenters that are not oxidized. Illustrative is the oxidation of the following diol to a carboxylic acid:

Oxidation of epoxy alcohols also occurs without degradation of the epoxide ring:

Under milder condition, oxidative reaction yields aldehydes instead. RuO4 readily converts secondary alcohols into ketones. Although similar results can be achieved with other cheaper oxidants such as PCC- or DMSO-based oxidants, RuO4 is ideal when a very vigorous oxidant is needed but mild conditions must be maintained.

RuO4 readily cleaves double bonds to yield carbonyl products, in a manner similar to ozonolysis. Osmium(VIII) oxide, a more familiar oxidant that is structurally similar to RuO4, does not cleave double bonds, instead producing vicinal diol products.

In terms of practical details, the substrate to be oxidized is typically dissolved in solvent such as CCl4, and acetonitrile is added as an aiding ligand to the catalytic cycle. Ether can then be added to precipitate and recover the ruthenium pre-catalyst.

Ruthenium tetroxide is used to expose latent fingerprints by turning to the brown/black ruthenium dioxide when in contact with fatty oils or fats contained in sebaceous contaminants of the print.[2]

Oxidative catalyst and mechanism

Although used as a direct oxidant, due to the relatively high cost of RuO4 it is also used catalytically with a cooxidant. For an oxidation of cyclic alcohols with RuO4 as a catalyst and bromate as a base, RuO4 is first activated by hydroxide:

RuO4 + OH → HRuO5

The reaction proceeds via a glycolate complex.

Related ruthenium compounds

Because RuO4 will readily decompose explosively at slightly elevated temperatures, most laboratories do not synthesize it directly, nor is it commercially available. Most laboratories instead use the anionic Ru(VII) derivative in the form of the salt of "TPAP" (tetrapropylammonium perruthenate), [N(C3H7)4]RuO4. TPAP is synthesized by oxidizing RuCl3 to RuO4 by NaBrO3 and isolated as the tetrapropylamine cation, which allows the salt to be used in organic solvents.

References

  1. ^ Pley, M.; Wickleder, M. S. (2005). "Two Crystalline Modifications of RuO4". Journal of Solid State Chemistry 178 (10): 3206–3209.  
  2. ^ Mashiko, K.; Miyamoto, T. (1998). "Latent Fingerprint Processing by the Ruthenium Tetroxide Method". Journal of Forensic Identification 48 (3): 279–290.  

Further reading

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